Measurement of the adduction constant by gas-liquid chromatography |
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| Authors: | X Feng S -K Wang J Shi |
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| Institution: | (1) Department of Chemical Engineering, Nanjing Institute of Chemical Technology, 210009 Nanjing, Jiangsu, People's Republic of China |
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| Abstract: | Summary The adduction constants for the following eight binary systems were measured by gas liquid chromatography, at different temperatures: tetrachloromethane/p-xylene, tetrachloromethane/pseudocumene, chloroform/p-xylene, chloroform/pseudocumene, chloroform/aniline, m-methylphenol/aniline, o-methylphenol/aniline, and o-chlorophenol/aniline. The relationships between the adduction constant and temperature were used to fit the enthalpies and entropies of adduct formation. |
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| Keywords: | Gas chromatography Determination of adduction contant Enthalpies and entropies |
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