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Surface transformation and photoinduced recovery in CdSe nanocrystals
Authors:Hess B C  Okhrimenko I G  Davis R C  Stevens B C  Schulzke Q A  Wright K C  Bass C D  Evans C D  Summers S L
Affiliation:Department of Physics and Astronomy, Brigham Young University, Provo, Utah 84062, USA.
Abstract:CdSe nanocrystals in solution and films can enter a metastable state in which the highly luminescent nanocrystals become dark. This change, which we attribute to a surface transformation, can be caused by heating or by changing the environment of the nanocrystals at room temperature. The metastable transformation is reversed upon illumination of above-band-gap light, at which point the nanocrystals are again highly luminescent.
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