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Aqueous‐Solution Route to Zinc Telluride Films for Application to CO2 Reduction
Authors:Youn Jeong Jang  Dr. Jae Young Kim  Won Yong Kim  Prof. Jeong Kon Seo  Prof. Sungjee Kim  Prof. Kun‐Hong Lee  Prof. Jae Sung Lee
Affiliation:1. Department of Chemistry/Chemical Engineering, Pohang University of Science and Technology (POSTECH), San 31, Hyoja‐Dong, Pohang, 790‐784 (South Korea);2. School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), 50 UNIST‐gil, Ulsan, 689‐798 (South Korea)
Abstract:As a photocathode for CO2 reduction, zinc‐blende zinc telluride (ZnTe) was directly formed on a Zn/ZnO nanowire substrate by a simple dissolution–recrystallization mechanism without any surfactant. With the most negative conduction‐band edge among p‐type semiconductors, this new photocatalyst showed efficient and stable CO formation in photoelectrochemical CO2 reduction at ?0.2–?0.7 V versus RHE without a sacrificial reagent.
Keywords:artificial photosynthesis  photocathodes  photoelectrochemical CO2 reduction  solution synthesis  zinc telluride
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