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Coaxing Solid‐State Phosphorescence from Tellurophenes
Authors:Dr Gang He  William Torres Delgado  Devon J Schatz  Dr Christian Merten  Arash Mohammadpour  Lorenz Mayr  Michael J Ferguson  Robert McDonald  Prof Dr Alex Brown  Prof Dr Karthik Shankar  Prof Dr Eric Rivard
Institution:1. Dept. of Chemistry, University of Alberta, 11227 Saskatchewan Dr., Edmonton, Alberta, T6G?2G2 (Canada);2. Dept. of Electrical and Computer Engineering, University of Alberta, Edmonton, Alberta, T6G 2V4 (Canada)
Abstract:The synthesis of the first examples of tellurophenes exhibiting phosphorescence in the solid state and under ambient conditions (room temperature and in air) is reported. Each of these main‐group‐element‐based emitters feature pinacolboronates (BPin) as ring‐appended side groups. The nature of the luminescence observed was also investigated using computational methods.
Keywords:boronic esters  main‐group elements  solid‐state phosphorescence  tellurophenes
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