Copper‐Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3‐Containing Alkyl Azides |
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| Authors: | Fei Wang Xiaoxu Qi Zhaoli Liang Dr. Pinhong Chen Prof. Dr. Guosheng Liu |
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| Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai, Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032 (China) |
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| Abstract: | A novel copper‐catalyzed intermolecular trifluoromethylazidation of alkenes has been developed under mild reaction conditions. A variety of CF3‐containing organoazides were directly synthesized from a wide range of olefins, including activated and unactivated alkenes, and the resulting products can be easily transformed into the corresponding CF3‐containing amine derivatives. |
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| Keywords: | alkenes azides copper fluorine synthetic methods |
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