A Mixed Molecular Building Block Strategy for the Design of Nested Polyhedron Metal–Organic Frameworks |
| |
| Authors: | Dan Tian Qiang Chen Dr Yue Li Dr Ying‐Hui Zhang Dr Ze Chang Prof?Dr Xian‐He Bu |
| |
| Institution: | 1. Department of Chemistry and TKL of Metal and Molecule‐Based Material Chemistry;2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071 (China) |
| |
| Abstract: | A mixed molecular building block (MBB) strategy for the synthesis of double‐walled cage‐based porous metal–organic frameworks (MOFs) is presented. By means of this method, two isostructural porous MOFs built from unprecedented double‐walled metal–organic octahedron were obtained by introducing two size‐matching C3‐symmetric molecular building blocks with different rigidities. With their unique framework structures, these MOFs provide, to the best of our knowledge, the first examples of double‐walled octahedron‐based MOFs. |
| |
| Keywords: | cobalt metal‐organic frameworks nickel synthetic methods |
|
