Fluorinated Alq3 derivatives with tunable optical properties |
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Authors: | Shi Yue-Wen Shi Min-Min Huang Jia-Chi Chen Hong-Zheng Wang Mang Liu Xiao-Dong Ma Yu-Guang Xu Hai Yang Bing |
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Institution: | Department of Polymer Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, PR China. |
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Abstract: | This communication reports that not only the emission colour but also the photoluminescence quantum yield of Alq3 can be tuned by introducing fluorine atoms at different positions; with fluorination at C-5 the emission is red-shifted with a tremendously decreased intensity, fluorination at C-6 causes a blue-shift with a significantly increased intensity, and fluorination at C-7 has a minor effect on both the colour and intensity of Alq3's emission. |
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