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Fluorinated Alq3 derivatives with tunable optical properties
Authors:Shi Yue-Wen  Shi Min-Min  Huang Jia-Chi  Chen Hong-Zheng  Wang Mang  Liu Xiao-Dong  Ma Yu-Guang  Xu Hai  Yang Bing
Institution:Department of Polymer Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, PR China.
Abstract:This communication reports that not only the emission colour but also the photoluminescence quantum yield of Alq3 can be tuned by introducing fluorine atoms at different positions; with fluorination at C-5 the emission is red-shifted with a tremendously decreased intensity, fluorination at C-6 causes a blue-shift with a significantly increased intensity, and fluorination at C-7 has a minor effect on both the colour and intensity of Alq3's emission.
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