A homoleptic hydrotris(methimazolyl)borate complex of titanium |
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| Authors: | Hill Anthony F Smith Matthew K |
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| Institution: | Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, Australia. a.hill@anu.edu.au. |
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| Abstract: | The reaction of Ti(2)(micro-Cl)(2)(thf)(2)(eta-C(8)H(8))(2)] with NaHB(mt)(3)] (mt = methimazolyl) provides the unusual salt Ti{HB(mt)(3)}(2)]TiCl(4)(thf)(2)], the cation of which features homoleptic Ti(III)S(6) coordination. |
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