| 稳定烯醇及其合成方法学 |
| |
| 引用本文： | 胡乔舒,席振峰. 稳定烯醇及其合成方法学[J]. 有机化学, 2008, 28(11): 1864-1874 |
| |
| 作者姓名： | 胡乔舒 席振峰 |
| |
| 作者单位： | 北京人学化学与分子工程学院,北京分子科学国家实验室,生物有机与分子工程教育部重点实验室,北京,100871 |
| |
| 摘 要： | 烯醇受环境因素和取代基的影响在一定条件下可以稳定存在. 研究稳定烯醇的结构特点、反应性质在有机化学理论研究和有机合成化学中有重要意义. 从影响烯醇稳定的因素以及稳定烯醇合成方法学的角度对该领域进行了综述, 分别讨论了芳基取代烯醇和脂肪基取代烯醇的稳定性及其合成方法.
|
| 关 键 词： | 烯醇 稳定性 互变异构 合成 |
| 收稿时间： | 2008-12-23 |
| 修稿时间： | 2008-04-01 |
Stable Enols and Their Synthetic Methodologies |
| |
| HU,Qiao-Shu,XI,Zhen-Feng. Stable Enols and Their Synthetic Methodologies[J]. Chinese Journal of Organic Chemistry, 2008, 28(11): 1864-1874 |
| |
| Authors: | HU Qiao-Shu XI Zhen-Feng |
| |
| Affiliation: | (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871) |
| |
| Abstract: | Enols can be stable or even isolable by bearing special substituents or in proper environments. The study of structures and chemical behavior of stable enols is important from both theoretical and synthetic points of view. Here, the stabilities and synthetic methodologies of aromatic and aliphatic enols are discussed. |
| |
| Keywords: | enol stability tautomerization synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
|
点击此处可从《有机化学》下载全文 |
|
