Magnetic susceptibility, specific heat and magnetic structure of CuNi2(PO4)2 |
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Authors: | Jaione Escobal José L Mesa Aitor Larrañaga María I Arriortua |
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Institution: | a Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, EHU. Apdo. 644, E-48080 Bilbao, Spain b Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco, EHU. Apdo. 644, E-48080 Bilbao, Spain c CITIMAC, Facultad de Ciencias, Universidad de Cantabria, Avenida de los Castros, 39005 Santander, Spain |
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Abstract: | The CuNi2(PO4)2 phosphate has been synthesized by the ceramic method at 800 °C in air. The crystal structure consists of a three-dimensional skeleton constructed from MO4 (MII Cu and Ni) planar squares and M2O8 dimers with square pyramidal geometry, which are interconnected by (PO4)3− oxoanions with tetrahedral geometry. The magnetic behavior has been studied on powdered sample by using susceptibility, specific heat and neutron diffraction data. The bimetallic copper(II)-nickel(II) orthophosphate exhibits a three-dimensional magnetic ordering at, approximately, 29.8 K. However, its complex crystal structure hampers any parametrization of the J-exchange parameter. The specific heat measurements exhibit a three-dimensional magnetic ordering (λ-type) peak at 29.5 K. The magnetic structure of this phosphate shows ferromagnetic interactions inside the Ni2O8 dimers, whereas the sublattice of Cu(II) ions presents antiferromagnetic couplings along the y-axis. The change of the sign in the magnetic unit-cell, due to the 1/2, 0, 1/2] propagation vector determines a purely antiferromagnetic structure. |
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Keywords: | Mixed Copper(II)-Nickel(II) phosphate Susceptibility Specific heat Magnetic structure |
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