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Magnetic properties of RY2Ni9 compounds and their hydrides (R=La, Ce)
Authors:V. Paul-Boncour,M. Latroche,A. Percheron-Gué  gan
Affiliation:Laboratoire de Chimie Métallurgique des Terres Rares, CNRS, 2-8 rue H. Dunant, 94320 Thiais, France
Abstract:The magnetic properties of the RY2Ni9 ternary alloys (R=La, Ce) and their hydrides have been investigated. Both LaY2Ni9 and CeY2Ni9 are ferromagnets with TC=15 and 92 K, respectively. Upon H absorption LaY2Ni9H12 becomes a Pauli paramagnet, whereas CeY2Ni9H8 remains ferromagnetic with an additional magnetic contribution of trivalent Ce atoms belonging to the MgZn2 units occupied by hydrogen atoms.
Keywords:Metal hydrides   Magnetism   Ce valence
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