有机HTDIOO分子LB膜结构的AFM研究

利用原子力显微镜（ＡＦＭ）对有机分子ＨＴＤＩＯＯ单层和多层ＬＢ膜结构进行了观察。实验结果表明，针尖与ＬＢ膜表面分子间的相互作用力会对成像的膜结构有影响。当悬臂针尖与ＬＢ膜表面分子的相互作用力较大时，针尖会扰动ＨＴＤＩＯＯ分子在单层ＬＢ膜中的有序排列。ＨＴＤＩＯＯ单层ＬＢ膜具有有序结构；而在多层ＬＢ膜中，ＨＴＤＩＯＯ分子则聚集在一起形成了一定的畴结构。

AFM Studies of HTDIOO Monomolecular Layer LB Films

The structures of HTDIOO molecular monolayer and multilayer LB films have been observed by atomic force microscopy (AFM) in molecular and nanometer scales. It demonstrates that large AFM probe tip force could damage the structure of HTDIOO LB films. Moreover, there is an ordered structure in HTDIOO monolayer LB film. While the HTDIOO molecules aggragate and form domains in multilayer LB film, which could be associated with the stripe magnetic sturcture formed in multilayer HTDIOO LB films observed with magnetic force microscopy(MFM).