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微乳液反应法制备草酸铜均匀微粒
引用本文:甘礼华,岳天仪,陈龙武,李光明,朱大章,周恩绚.微乳液反应法制备草酸铜均匀微粒[J].物理化学学报,1998,14(2):97-102.
作者姓名:甘礼华  岳天仪  陈龙武  李光明  朱大章  周恩绚
作者单位:Department of Chemistry,Tongji University,Shanghai 200092,The ninth Department,Beijing University of Aeronautics and Astronautics,Beijing 100083
摘    要:在Triton x-100-n-C6H13OH/c-C6H12/水溶液(硝酸铜或草酸)体系W/O微乳液中,通过变换草酸和硝酸铜溶液的速度、温度和pH值而获得超细、方形的、管状的以及网络状的多种形态粒子,特别是制备得到方形和管状两种均匀胶体粒子。研究了影响粒子形态和大小的因素。

关 键 词:微乳液  草酸铜  均匀胶体微粒  制备  
收稿时间:1997-03-14
修稿时间:1997-06-24

Studies on the Preparation of Cupric Oxalate Uniform Colloidal Particles by the Method of Microemulsion Reaction
Gan Lihua, Yue Tianyi, Chen Longwu, Li Guangming, Zhu Dazhang.Studies on the Preparation of Cupric Oxalate Uniform Colloidal Particles by the Method of Microemulsion Reaction[J].Acta Physico-Chimica Sinica,1998,14(2):97-102.
Authors:Gan Lihua  Yue Tianyi  Chen Longwu  Li Guangming  Zhu Dazhang
Institution:Department of Chemistry,Tongji University,Shanghai 200092|The ninth Department,Beijing University of Aeronautics and Astronautics,Beijing 100083
Abstract:Cupric oxalate uniform colloidal particles with different shapes and sizes, such asultrafine. square. pipe-like and network-like, were prepared in the Triton X-100 n-C6H13OH/c C6H12/Water solution (oxalic acid or cupric nitrate W/o microemulsion system by adjusting theconcentration, pH value and temperature of oxalic acid and cupric nitrate solutions. What shouldbe particularly mentioned is the preparation of two types of uniform colloidal particles whoseshapes are square and pipe-like respectively. The factors which influence the shapes and sizes ofparticles are under vigorous control.
Keywords:Microemulsion  Cupric oxalate  Unifrom colloidal particle  Preparation
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