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掺铜二氧化钛光催化剂的XPS研究
引用本文:吴树新,马智,秦永宁,何菲,贾立山,张彦军.掺铜二氧化钛光催化剂的XPS研究[J].物理化学学报,2003,19(10):967-969.
作者姓名:吴树新  马智  秦永宁  何菲  贾立山  张彦军
作者单位:School of Chemical Engineering and Technology,Tianjin University; United Institute of Nankai University and Tianjin University; State Key Laboratory of C1 Chemical Technology of Tianjin University, Tianjin 300072
摘    要:利用浸渍法制备了铜掺杂的二氧化钛,以乙酸为模型物研究了催化剂的光催化活性,利用XPS结果对改性后的催化剂进行了分析.结果表明,改性后的催化剂表面吸附氧的提高和Cu+/Cu2+的共存有利于光生载流子的分离和界面电子转移,因而改善了催化剂的光催化性能.

关 键 词:光催化氧化  乙酸  铜掺杂  二氧化钛  XPS  
收稿时间:2003-03-24
修稿时间:2003-05-30

XPS Study of Copper Doping TiO2 Photocatalyst
Wu Shu Xin Ma Zhi, Qin Yong Ning, He Fei Jia Li Shan Zhang Yan Jun.XPS Study of Copper Doping TiO2 Photocatalyst[J].Acta Physico-Chimica Sinica,2003,19(10):967-969.
Authors:Wu Shu Xin Ma Zhi    Qin Yong Ning  He Fei Jia Li Shan Zhang Yan Jun
Institution:School of Chemical Engineering and Technology,Tianjin University; United Institute of Nankai University and Tianjin University; State Key Laboratory of C1 Chemical Technology of Tianjin University, Tianjin 300072
Abstract:The copper doped titanium dioxide was prepared by immersion method.Photocatalytic activity was investigated with acetic acid as a model reactant,and the photocatalyst was analyzed by means of XPS.The enhanced degradation rate of acetic acid is attributed to increased charge separation and interfacial charge transfer rate on the surface of the doped photocatalyst.
Keywords:Photocatalytic oxidation  Acetic acid  Copper ion doping  Titanium dioxide  XPS
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