Nanoconfinement crystallization of frustrated alkyl groups: crossover of mesophase to crystalline structure |
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| Authors: | Shi Haifeng Wang Haixia Xin John H Zhang Xingxiang Wang Dujin |
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| Institution: | State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Institute of Functional Fiber, Tianjin Polytechnic University, Tianjin 300160, China. haifeng.shi@gmail.com |
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| Abstract: | Crossover of mesophase to crystalline structure in the nanoconfinement crystallization process of frustrated side groups elucidates the critical crystal thickness d(c) or the length scale of side groups, which defines the transition process from mesophase (hexagonal and monoclinic phase) to crystalline phase (orthorhombic phase) of confined CH(2) sequences in a given crystal size restriction. |
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