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Fluorotris(trifluoromethylsulfonyl)methane: synthesis, characterization and reactivity |
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| Authors: | Peer Kirsch,Matthias Bremer,Herwig A Buchholz,Enno Lork,Gerd-Volker Rö schenthaler |
| Affiliation: | a Liquid Crystals Division, Merck KGaA, D-64271 Darmstadt, Germany b Pigments Division, Merck KGaA, D-64271 Darmstadt, Germany c New Business Chemicals, Merck KGaA, D-64271 Darmstadt, Germany d University of Southern California, Los Angeles, CA, USA e Institute for Inorganic and Physical Chemistry, University of Bremen, D-28359 Bremen, Germany |
| Abstract: | The hitherto elusive title compound was synthesized and characterized with the aim to study its potential as a carbon-based (“CF-type”) electrophilic fluorination reagent. A detailed discussion of its structure, properties and reactivity is based on experimental studies as well as on molecular modeling. |
| Keywords: | Direct fluorination Electrophilic fluorination Fluorination reagents Density functional calculations X-ray structure analysis |
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