Synthesis and characterisation of bis(pentafluorophenyl)antimony(V) cations, [(C6F5)2SbL3]期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Synthesis and characterisation of bis(pentafluorophenyl)antimony(V) cations, [(C₆F₅)₂SbL₃]

Authors:	Kiran Singhal Ravi Kant Prem Raj AK Goswami

Institution:	Department of Chemistry, University of Lucknow, Lucknow 226007, UP, India

Abstract:	Pentacoordinate complex cations of the general formula (C₆F₅)₂SbL₃]³⁺ stabilized as solid salts in combination with tetraphenylborate (BPh₄), tetrafluorobroate (BF₄) anions, where L=DMSO, Ph₃AsO, PyO, DMF, α-, β- and γ-picoline have been isolated. The newly formed complexes were characterized by elemental analysis, molar conductance measurements, solid-state IR and and NMR. From these results, a five-fold coordination around antimony was required.

Keywords:	Bis(pentafluorophenyl)antimony(V) cations [(C₆F₅)₂SbL₃]³⁺ IR _method=retrieve& _eid=1-s2 0-S0022113903000940& _mathId=si5 gif& _pii=S0022113903000940& _issn=00221139& _acct=C000053510& _version=1& _userid=1524097& md5=d374caec925cfaea98a1cb558d398a9e')" style="cursor:pointer " alt="Click to view the MathML source" title="Click to view the MathML source">els-cdn com/content/image/1-s2 0-S0022113903000940-si5 and gif"> and _method=retrieve& _eid=1-s2 0-S0022113903000940& _mathId=si6 gif& _pii=S0022113903000940& _issn=00221139& _acct=C000053510& _version=1& _userid=1524097& md5=0951d6fa15d8aa43bc5fee3d30001ef4')" style="cursor:pointer " alt="Click to view the MathML source" title="Click to view the MathML source">els-cdn com/content/image/1-s2 0-S0022113903000940-si6 NMR" target="_blank">gif"> NMR 1:3 Electrolytes Trigonal bipyramidal
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