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Magnesium Oxide-Catalyzed Conversion of Chitin to Lactic Acid
Authors:Kodchakon Kun-asa  Prof Prasert Reubroycharoen  Dr Kiyoyuki Yamazaki  Dr Naoki Mimura  Dr Osamu Sato  Dr Aritomo Yamaguchi
Institution:1. Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST), 4-2-1 Nigatake, Miyagino, Sendai, 983-8551 Japan

Department of Chemical Technology, Faculty of Science, Chulalongkorn University Pathumwan, Bangkok, 10330 Thailand;2. Department of Chemical Technology, Faculty of Science, Chulalongkorn University Pathumwan, Bangkok, 10330 Thailand;3. Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST), 4-2-1 Nigatake, Miyagino, Sendai, 983-8551 Japan

Abstract:Although chitin, an N-acetyl-D-glucosamine polysaccharide, can be converted to valuable products by means of homogeneous catalysis, most of the chitin generated by food processing is treated as industrial waste. Thus, a method for converting this abundant source of biomass to useful chemicals, such as lactic acid, would be beneficial. In this study, we determined the catalytic activities of various metal oxides for chitin conversion at 533 K and found that MgO showed the highest activity for lactic acid production. X-ray diffraction analysis and thermogravimetry-differential thermal analysis showed that the MgO was transformed to Mg(OH)2 during chitin conversion. The highest yield of lactic acid (10.8 %) was obtained when the reaction was carried out for 6 h with 0.5 g of the MgO catalyst. The catalyst could be recovered as a solid residue after the reaction and reused twice with no decrease in the lactic acid yield.
Keywords:biomass  chitin conversion  heterogeneous catalysis  lactic acid  magnesium oxide
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