Chain transfer to solvent in BN 2-vinylnaphthalene radical polymerization |
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Authors: | Yuyang Ji Rebekka S Klausen |
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Institution: | Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, USA |
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Abstract: | The synthesis of vinyl alcohol copolymers is limited due to the poor radical reactivity of vinyl acetate (VAc), the traditional precursor to polyvinyl alcohol (PVA). Main group monomers such as BN 2-vinylnaphthalene (BN2VN) have attracted attention as alternatives to VAc to form side chain hydroxyls via oxidation, but outstanding questions of molecular weight control remain. Herein we report systematic investigation of solvent, temperature, and initiator concentration as factors influencing BN2VN degree of polymerization. We find increased chain transfer to toluene, hypothesized to arise from differences in radical stabilization and reactivity by aromatic and BN aromatic rings. As a result of these combined efforts, high molecular weight (Mw ~ 105 g mol?1) BN2VN homopolymers and BN2VN-styrene copolymers were obtained. |
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Keywords: | boranes copolymerization hydrophilicity radical reactions solvent effects |
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