Model Studies on the Ozone-Mediated Synthesis of Cobalt Oxide Nanoparticles from Dicobalt Octacarbonyl in Ionic Liquids |
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Authors: | Ralf Schuster Tobias Wähler Dr Miroslav Kettner Dr Friederike Agel Dr Tanja Bauer Prof Peter Wasserscheid Prof Jörg Libuda |
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Institution: | 1. Interface Research and Catalysis, Erlangen Center for Interface Research and Catalysis (ECRC), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany;2. Institute of Chemical Reaction Engineering, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany |
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Abstract: | Low-temperature synthesis in ionic liquids (ILs) offers an efficient route for the preparation of metal oxide nanomaterials with tailor-made properties in a water-free environment. In this work, we investigated the role of 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide C4C1Pyr]NTf2] in the synthesis of cobalt oxide nanoparticles from the molecular precursor Co2(CO)8 with ozone. We performed a model study in ultra-clean, ultrahigh vacuum (UHV) conditions by infrared reflection absorption spectroscopy (IRAS) using Au(111) as a substrate. Exposure of the pure precursor to ozone at low temperatures results in the oxidation of the first layers, leading to the formation of a disordered CoxOy passivation layer. Similar protection to ozone is also achieved by deposition of an IL layer onto a precursor film prior to ozone exposure. With increasing temperature, the IL gets permeable for ozone and a cobalt oxide film forms at the IL/precursor interface. We show that the interaction with the IL mediates the oxidation and leads to a more densely packed CoxOy film compared to a direct oxidation of the precursor. |
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Keywords: | cobalt oxide ionic liquids IR spectroscopy low temperature synthesis ozone |
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