Mechanochemistry for Energy Materials: Impact of High-Energy Milling on Chemical,Electric and Thermal Transport Properties of Chalcopyrite CuFeS2 Nanoparticles |
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Authors: | Prof Peter Balá? Dr Erika Dutková Dr Matej Balá? Dr Róbert D?unda Dr Ji?í Navrátil Dr Karel Kní?ek Dr Petr Levinský Dr Ji?í Hejtmánek |
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Institution: | 1. Institute of Geotechnics, Slovak Academy of Sciences, Watsonova 45, 04001 Ko?ice, Slovakia;2. Institute of Materials Research, Slovak Academy of Sciences, Watsonova 47, 04001 Ko?ice, Slovakia;3. Institute of Physics of the Czech Academy of Sciences, Cukrovarnická 10, 16200 Prague, Czech Republic |
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Abstract: | Chalcopyrite CuFeS2, a semiconductor with applications in chemical sector and energy conversion engineering, was synthetized in a planetary mill from elemental precursors. The synthesis is environmentally friendly, waste-free and inexpensive. The synthesized nano-powders were characterized by XRD, SEM, EDX, BET and UV/Vis techniques, tests of chemical reactivity and, namely, thermoelectric performance of sintered ceramics followed. The crystallite size of ~13 nm and the strain of ~17 were calculated for CuFeS2 powders milled for 60, 120, 180 and 240 min, respectively. The evolution of characteristic band gaps, Eg, and the rate constant of leaching, k, of nano-powders are corroborated by the universal evolution of the parameter SBET/X (SBET-specific surface area, X-crystallinity) introduced for complex characterization of mechanochemically activated solids in various fields such as chemical engineering and/or energy conversion. The focus on non-doped semiconducting CuFeS2 enabled to assess the role of impurities, which critically and often negatively influence the thermoelectric properties. |
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Keywords: | chalcopyrite energy materials mechanochemistry semiconductors thermoelectrics |
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