Macroreticular p-(omega-sulfonic-perfluoroalkylated) polystyrene ion-exchange resins: a new type of selective solid acid catalyst |
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| Authors: | Lin Zhenghuan Zhao Chengxue |
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| Institution: | Department of Chemistry, Shanghai Jiaotong University, 800 Dongchuan Road, Shanghai 200240, China. |
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| Abstract: | Macroreticular p-(omega-sulfonic-perfluoroalkylated) polystyrene (FPS) cation-exchange resins have been synthesized by sequential p-perfluoroalkylation of macroreticular polystyrene (PS) with omega-fluorosulfonylperfluorodiacyl peroxide 2, hydrolysis and acidification; the fluorinated mesoporous resins exhibited higher activity and selectivity than commercial Amberlyst 36 and Nafion NR50 in the cyclization of pseudoionone. |
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