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Study of pyrolysis and incineration of disposable plastics using combined TG/FT-IR technique
Authors:P S Bhandare  B K Lee  K Krishnan
Institution:(1) Digilab Division, Bio-Rad Laboratories, 237 Putnam Avenue, 02139 Cambridge, MA, USA;(2) Department of Civil and Environmental Engineering, University of Ulsan, San 29, Mu-Geo, Nam-Gu, Ulsan, Korea
Abstract:Thermogravimetric analysis (TG) provides information regarding mass changes in the sample resulting from heat treatment under controlled environment. However, it does not provide any chemical information regarding the gases evolved during the thermal degradation. Using FT-IR spectrometry in combination with TG, it is often possible to identify the evolved gases, and also monitor their evolution profiles during thermal degradation. In this study, we present the TG/FT-IR combined analysis of incineration and pyrolysis of some common plastics such as high density polyethylene (HDPE), polyvinyl chloride (PVC), polyethylene terephthalate (PET), and polystyrene (PS). This study demonstrates the utility of such combined analysis in providing useful information regarding the use of thermal treatment for recycling or incineration.
Keywords:disposable  evolved gases  FT-IR spectroscopy  polymers  TG
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