Effect of High Pressure on the Kinetics and Mechanism of Thermolysis of Organic Peroxides in Solution |
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| Authors: | Antonovskii V L Zhulin V M |
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| Institution: | (1) Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia;(2) Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119992, Russia |
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| Abstract: | This review analyzes published data and experimental results obtained by the authors concerning the effect of high pressure on the chemical kinetics of thermal decomposition of the main types of organic and organosilicon peroxides in solution. The volume effect of activation was found to depend on the mechanism of peroxide decomposition and on the properties of solvents. |
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