Polymer electrolytes based on copolymer of poly(ethylene glycol) dimethacrylate and imidazolium ionic liquid |
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| Authors: | Zhenglin Tang Li Qi Guitian Gao |
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| Affiliation: | 1. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;2. School of Materials Science and Engineering, Jilin University, Changchun 130025, China |
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| Abstract: | Polymer electrolytes based on the copolymer of N-vinylimidazolium tetrafluoroborate (VyImBF4) and poly(ethylene glycol) dimethacrylate (PEGDMA) have been prepared. Ethylene carbonate (EC) and LiClO4 are added to form gel polymer electrolytes. The chemical structure of the samples and the interactions between the various constituents are studied by FT-IR. TGA results show that these polymer electrolytes have acceptable thermal stability, are stable up to 155 °C. Measurements of conductivity are carried out as a function of temperature, VyImBF4 content in poly(VyImBF4-co-PEGDMA), and the concentration of EC and LiClO4. The conductivity increases with PEGDMA and EC content. The highest conductivity is obtained with a value of 2.90 × 10? 6 S cm? 1 at room temperature for VP1/EC(25 wt.%)–LiClO4 system, corresponding to the LiClO4 concentration of 0.70 mol kg? 1 polymer. |
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