Theory of cyclic voltammetry for electrochemical nucleation and growth |
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| Authors: | Vladimir A. Isaev Olga V. Grishenkova Yurii P. Zaykov |
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| Affiliation: | 1.Institute of High Temperature Electrochemistry,Ural Branch of the Russian Academy of Sciences,Ekaterinburg,Russia;2.Ural Federal University,Ekaterinburg,Russia |
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| Abstract: | The theory of cyclic voltammetry for processes of 3D nucleation, diffusion-controlled growth, and dissolution is proposed. The cases of single metal cluster formation and multiple nucleation are studied. The main features of cyclic voltammograms are analyzed: current increase on forward scan during nucleation, nucleation loop, maximum cathode current on reverse scan, and anodic peak of metal stripping. |
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