New supramolecular isomers with 2D 4(4) square-grid and 3D 6(5).8 frameworks in a one-pot synthesis; reversible solvent uptake and intriguing luminescence properties |
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| Authors: | Wang Chih-Chieh Lin Wei-Zeng Huang Wei-Ting Ko Mei-Ju Lee Gene-Hsiang Ho Mei-Lin Lin Chun-Wei Shih Chun-Wei Chou Pi-Tai |
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| Institution: | Department of Chemistry, Soochow University, Taipei 111, Taiwan. ccwang@scu.edu.tw |
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| Abstract: | Two supramolecular isomers of Ni(4-bpd)(2)(NCS)(2)] (4-bpd = 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene) with 2D 4(4) square-grid and 3D 6(5).8 frameworks are co-crystallized in a one-pot reaction, both of which exhibit interesting luminescence properties and reversible adsorption-desorption with respect to guest solvents. |
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