Relative reactivities of glycerophosphates towards permanganate in perchloric acid medium |
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| Authors: | Kalyan Kali Sen Gupta Ambikesh Mahapatra Balaram Ghosh |
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| Affiliation: | (1) Department of Chemistry, Jadavpur University, 700032 Catcutta, India |
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| Abstract: | Summary The reactivities of  - and  -glycerophosphates towards MnO4– in HClO4 medium have been examined. The reactions between glycerophosphates and MnO4– are first order with respect to [glycerophosphate], [MnO4–] and [H+]. There is no evidence for cleavage of the C–O–P bond rather than the terminal –CH2OH group being oxidized to the respective phosphoglyceraldehyde. |
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