Deposition of refractory coatings on carbon fibers from volatile Hf-containing precursors |
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Authors: | N B Morozova N V Gelfond S V Sysoev N I Baklanova N Z Lyakhov |
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Institution: | (1) Materials Team Leader, SELEX Sensors and Airborne Systems Infrared Ltd., Millbrook Industrial Estate, PO Box 217, SO15 0EG Southampton, Hampshire, UK;(2) Department of Chemistry, University of Wales, Bangor, LL57 2UW Gwynedd, UK;(3) Functional Materials Research Centre, Department of Engineering, University of Liverpool, Brownlow Hill, L69 3BX Liverpool, UK |
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Abstract: | The possibility to modify the carbon fiber surface by refractory hafnium compounds via chemical vapor deposition of volatile
metal-organic complexes is studied. Thermodynamic modeling is applied to calculate the CVD diagram of the Hf-C-O-F-H system
within a 25–1200°C temperature range, 10−1–10 Torr pressure range, and 0–2000 hydrogen/precursor vapor ratio. It is demonstrated that the deposition should be carried
out at the maximum hydrogen flow and the minimum total pressure in the system. SEM and AFM techniques are used to examine
the morphology and topography of the coatings on the fibers. Continuous coatings that are uniform in length and diameter of
monofilaments and are tightly bound to them are obtained. |
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