Syntheses,Crystal Structure and Luminescent Properties of Co-ordination Networks Based on Copper(I) Iodide Clusters from 1, 4-Bis(imidazole-1-ylmethyl)benzene |
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| Authors: | Tao Li Shao-Wu Du |
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| Affiliation: | (1) School of Life Sciences, Fujian Agriculture and Forestry University, FuZhou, Fujian, 350002, P.R. China;(2) State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P.R. China |
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| Abstract: | This paper presents novel and distinctive Copper(I) iodide polymers with intriguing structure motifs, constructed from 1, 4-bis(imidazole-1-ylmethyl)benzene (bix). Treatment of bix with CuI generated [(Cu4I4)(bix)2] n 1, whose X-ray single crystal structural determination revealed a novel 2-D battlement-like sheet structure with square grids based on distorted cubane-like Cu4I4 clusters. The structural features and photoluminescence of the complexes are discussed. The present finding may provide insight into the coordination versatility of copper(I) halide clusters with N-donor ligands and an inspiration for the self-assembly of novel supramolecular networks based on copper(I) halide clusters. |
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| Keywords: | Crystal structure Supramolecular (4,4) Topology Luminescence |
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