Sr(3)Co(2)O(4.33)h(0.84): an extended transition metal oxide-hydride |
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| Authors: | Helps Rebecca M Rees Nicholas H Hayward Michael A |
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| Institution: | Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, OX1 3QR, United Kingdom. |
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| Abstract: | Reaction of the n = 2 Ruddlesden-Popper oxide Sr(3)Co(2)O(5.80) with CaH(2) yields an extended oxide-hydride phase: Sr(3)Co(2)O(4.33)H(0.84). Neutron powder diffraction data reveal the material adopts a body-centered orthorhombic structure (Immm: a = 3.7551(5) ?, b = 3.7048(4) ?, c = 21.480(3) ?) in which the hydride ions are accommodated within disordered CoO(1.16)H(0.46) layers. Low temperature neutron powder diffraction data show no evidence for long-range magnetic order, suggesting the chemical disorder in the anion lattice of the material leads to magnetic frustration. |
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