Redetermination de la structure cristalline du tetrafluoroantimonate III de sodium NaSbF4 - interaction liaison fluor-paire electronique libre |
| |
| Authors: | N Habibi B Bonnet B Ducourant |
| |
| Institution: | Laboratoire de Chimie Analytique, Faculté Technique de Téhéran Iran;Laboratoire des Acides Minéraux L.A. 79, Université des Sciences et Techniques du Languedoc, Place E. Bataillon, 34060 Montpellier Cédex France |
| |
| Abstract: | The crystal structure of NaSbF4 has been redetermined by X-ray diffraction. The coordination about antimony is AX6E with a 2.2.2.1 geometry. The units are linked by fluorine bridges and form a double layer perpendicular to the a axis. Infrared and Raman spectra were recorded and are discussed in terms of the distorted octahedral arrangement of fluorines about each antimony. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
