Reactions of hydridosilacyclobutanes with low-valent complexes of iron or platinum |
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| Authors: | Colin S Cundy Michael F Lappert |
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| Institution: | School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ Great Britain |
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| Abstract: | Unstable transition metal compounds formed from hydridosilacyclobutanes are described: 1-methyl-1-silacyclobutane reacts with nonacarbonyldiiron to give the complexes Fe(CO)4(H){H2}] and (H)Me}(CO)4], and with bis(triphenylphosphine)(ethylene)platinum(0) to give Pt(H)(PPh3)2{H2}]. |
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