Fundamentals of lead acid cells: Part IV. The reduction of porous PbO2 electrodes in sulphuric acid |
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| Authors: | P Casson NA Hampson K Peters |
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| Institution: | Department of Chemistry, University of Technology, Loughborough, Leicestershire LE 11 3TU (England);Chloride Technical Ltd., Wynne Avenue, Swinton, Manchester M27 2HB (England) |
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| Abstract: | The reduction behaviour of porous lead dioxide electrodes is shown to be independent of rotation speed in a large excess of 5 M H2SO4. The reduction peak is broadened by the porosity. This porosity broadening is interpreted in terms of the reaction being driven more deeply into the pore structure as the front of the electrode becomes progressively more ressstive. The effect of different potential sweep rates on the current response and the effects of progressive redox cycles can be fully explained on this model. |
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