Triosmium-induced dehydrogenation of triethylamine. The crystal structure of HOs3 (CO)10 (−CHCH+NEt2) |
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| Authors: | John R. Shapley Mamoru Tachikawa Melvyn Rowen Churchill Romana A. Lashewycz |
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| Affiliation: | Department of Chemistry, University of Illinois, Urbana, Illinois 61801 U.S.A.;Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14214 U.S.A. |
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| Abstract: | The reaction of Os3 (CO)10(NCCH3)2 and triethylamine provides H2 Os3 (CO)10 and HOs3 (CO)10(CHCHNEt2) in equimolar amounts. The structure of the latter compound has been shown to involve an iminium ion center anchored to the Os3 framework by a bridging (substituted) methylene moiety. |
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