Methyl group replacement on pentamethylantimony with organophosphorus substituents |
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| Authors: | Guy E Graves John R Van Wazer |
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| Institution: | Department of Chemistry, Vanderbilt University, Nashville, Tennessee 37235 U.S.A. |
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| Abstract: | Phosphinic and phosphonic acids were treated with pentamethylantimony to replace one of its methyl groups (with formation of methane) to give the following new compounds: (CH3SbOP(O)(C6H5)2, (CH3)4SbOP(O)(OH)CH3, and (CH3)4SbOP(O)(OH)C6H5). The latter two compounds are associated, presumably through hydrogen bonding. |
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