Optically active transition metal complexes: LVI. Preparation and Stereochemistry of (+)578- and (-)578-(n-C6H6RuX(Me) [Ph2PNHCH(Me) (Ph)], where x = Cl,SnCl3期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Optically active transition metal complexes: LVI. Preparation and Stereochemistry of (+)578- and (-)578-(n-C6H6RuX(Me) [Ph2PNHCH(Me) (Ph)], where x = Cl,SnCl3

Authors:	Henri Brunner Robert G. Gastinger

Affiliation:	Institut für Chemie der Universität Regensburg, D-8400 Regensburg, Universitätsstrasse 31 B.R.D.

Abstract:	The synthesis and resolution of (+)₅₇₈- and (-)₅₇₈-(η-C₆H₆)RuCl(Me) [Ph₂PNHCH(Me) (Ph)] is described. Insertion of anhydrous SnCl₂ into the Ru-Cl bond yielded (+)₅₇₈- and (-)₅₇₈-(η-C₆H₆)RuSnCl₃(Me)-[Ph₂PNHCH(Me) (Ph)], the stereoselectivity of which is dependent on the reaction conditions. All the new complexes were found to be configurationally stable in a wide variety of solvents up to 60°C./

Keywords:	M.H. Soulard
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