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On the synthesis of the N2F+5 cation. A critical comment on the paper by Toy and Stringham.
Authors:KO Christe  CJ Schack  RD Wilson
Institution:Rocketdyne, A Division of Rockwell International, Canoga Park, California 91304 USA
Abstract:Toy and Stringham recently reported 1] the synthesis of N2F+5 (CF3)3CO-, a salt containing the novel pentafluorohydrazinium cation. This cation would be of significant academic and practical interest 2] since it would constitute the first known example of a substituted NF+4 cation, i.e. an NF+4 cation in which a fluorine ligand is replaced by an NF2 group. According to the authors of 1], N2F+5(CF3)3CO- was formed in a very unusual reaction involving the transfer of a fluorine cation from (CF3)3COF to N2F4 according to:
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