Adsorption and dissociation equilibrium of benzoic acid on the mercury electrode |
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Authors: | J. Dojlido M. Dmowska-Stańczak Z. Galus |
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Affiliation: | Laboratory of Electroanalytical Chemistry, Institute of Fundamental Problems ofChemistry, University of Warsaw, Pasteura 1, 02093 Warsaw (Poland) |
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Abstract: | Adsorption of benzoic acid at the mercury electrode was studied in a wide pH range. The adsorption isotherms of benzoic acid from electrocapillary and capacity measurements were calculated. From the dependence of capacitance and potential of zero charge on pH the pKel of benzoic acid was determined. |
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