Synthesis and reactions of the transition metal substituted tin hydride HSn[Mo(CO)3C5H5]3 |
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| Authors: | Carl D Hoff John W Connolly |
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| Institution: | Department of Chemistry,University of Missouri at Kansas City, Kansas City, MO 64110 U.S.A. |
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| Abstract: | Reaction of HMo(CO)3C5H5 and Sn(C5H5)2 produces the tin hydride HSnMo(CO)3C5H5]3 (I). Reaction of I with CCl4, CHCl3, or CH2Cl2 gives ClSnMo(CO)3C5H5]3 (II). With hydrogen chloride the hydride I reacts to produce the dichloride Cl2SnMo(CO)3C5H5]2. The first step in this reaction is cleavage of the SnH bond to produce the chloride II. The hydride I reacts with acetic acid to produce the diacetate (CH3COO)2SnMo(CO)3C5H5]2. |
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| Keywords: | To whom correspondence should be addressed |
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