Synthesis and phase behaviour of poly(propylene imine) dendromesogens of lowest generations |
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| Authors: | M S Gruzdev A I Alexandrov T V Pashkova U V Chervonova |
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| Institution: | 1. G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Ivanovo, Russian Federation;2. Ivanovo State University, Ivanovo, Russian Federation;3. Ivanovo Fire Rescue Academy of GFS MES of Russia, Ivanovo, Russian Federation |
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| Abstract: | Liquid crystal poly(propylene imine) dendrimers of the zero (D0) and the first (D1) generations were synthesised and structurally characterised by elemental analysis, FT-IR and nuclear magnetic resonance (NMR) spectroscopy, and mass spectrometry (MALDI-ToF). The phase behaviour of all the compounds was studied using polarisation microscopy and differential scanning calorimetry. Their structures were investigated by X-ray diffraction method by direct magnetic field influence. Analysis of diffraction patterns was carried out using the paracrystal model of Hosemann and the Fonk cluster model. Structural simulation and diffraction calculations on the models were used for determining the layer structure parameters of the dendrimers. Temperature behaviour of the structural parameters was considered in the interval from room temperature to isotropic melting temperature. It was determined that only the dendrimer of zero generation can be oriented by magnetic field. The schemes of phase transformations of the dendrimers look like: Cr→159°С→Sm-C→274°С→I for D0 and G→55–66°С→Sm-F→108°С→Sm-C→274°С→I for D1. |
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| Keywords: | Liquid crystalline dendrimers X-ray diffraction phase transitions of the first and the second order smectic mesophases |
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