Synthesis and properties of Fe(II), Ni(II), Co(II), and Zn(II) chelates with 4-nitrosemicarbazide |
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| Authors: | S. G. Il’yasov A. A. Lobanova N. I. Popov I. V. Kazantsev V. L. Varand S. V. Larionov |
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| Affiliation: | (1) Institute of Problems of Chemical Power Engineering Technologies, Siberian Branch, Russian Academy of Sciences, ul. Sotsialisticheskaya 1, Biisk, Altai Krai, Russia;(2) Altai Federal Research and Production Center, Federal State Unitary Enterprise, Biisk, Altai krai, Russia;(3) Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia |
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| Abstract: | Chelates M(O2NNCONHNH2)2 · 2H2O (M = Fe, Co, Ni, Zn) were prepared by the reactions of 4-nitrosemicarbazide with appropriate 3d transition metal salts. The structures of the compounds were suggested on the basis of data obtained by physicochemical methods. The compounds obtained were shown to be energetic substances. |
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