Structural similarities and differences among mixed-metal clusters containing a single M(PPh3) (M = Cu, Ag or Au) fragment |
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| Authors: | Ian D Salter F Gordon A Stone |
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| Institution: | Department of Inorganic Chemistry, University of Bristol, Bristol BS8 1TS Great Britain |
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| Abstract: | The heteronuclear metal clusters H3MRu4(CO)12(PPh3)] and MFe3(μ-COMe)(CO)10(PPh3)] (M = Cu, Ag or Au) have been prepared; the gold-tetraruthenium cluster has a different metal core geometry to that adopted by the copper and silver analogues, whereas all three iron-Group IB mixed-metal clusters have the same geometry. |
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