Kinetics and mechanism of homogeneous catalytic oxidation of pyrocatechol in aqueous solutions containing Cu(II) and histidine |
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| Authors: | V. M. Vorotyntsev O. K. Biryukovich E. P. Kuznetsova |
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| Affiliation: | (1) Institute of Physical Chemistry, Kiev, USSR |
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| Abstract: | Kinetic studies of pyrocatechol oxidation by oxygen in weakly acidic aqueous solutions containing pyrocatechol, Cu(II) ions and histidine, indicate that the reaction involves mixed copper-pyrocatechol histidine complexes. The proposed mechanism of the process agrees with the kinetic relationships obtained.
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