| Ln(Ⅲ)与2-羟基-1-萘醛缩蛋氨酸盐及邻菲咯啉三元配合物的合成与表征 |
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| 引用本文： | 范玉华,郝锐,毕彩丰,马玉祥. Ln(Ⅲ)与2-羟基-1-萘醛缩蛋氨酸盐及邻菲咯啉三元配合物的合成与表征[J]. 合成化学, 2003, 11(3): 230-232,236 |
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| 作者姓名： | 范玉华 郝锐 毕彩丰 马玉祥 |
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| 作者单位： | 1. 中国原子能科学研究院,北京,102314;济南大学化学与环境工程学院,山东,济南,250022
2. 济南大学化学与环境工程学院,山东,济南,250022 |
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| 摘 要： | 合成了稀土硝酸盐与希夫碱盐2-羟基-1-萘醛缩蛋氨酸钾(以KL表示)及邻菲咯啉(Phen)的四种固体三元配合物。通过元素分析，IR，UV，DTA-TG及摩尔电导分析等手段确定配合物的组成为[Ln(L)(Phen)(NO3)(H2O)]NO3(Ln＝Gd，Dy，Er，Yb)，并对它们的配合方式及某些物理和化学性质进行了研究。
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| 关 键 词： | 稀土硝酸盐 希夫碱 三元配合物 |
| 文章编号： | 1005-1511(2003)03-0230-03 |
Synthesis and Characterization of Ln(Ⅲ) Ternary Complexes with 2-Hydroxy-1-naphthaldehyde-methionine and O-Phenanthroline Hydrate |
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| FAN Yu hua ,,HAO Rui ,BI Cai feng ,MA Yu xiang. Synthesis and Characterization of Ln(Ⅲ) Ternary Complexes with 2-Hydroxy-1-naphthaldehyde-methionine and O-Phenanthroline Hydrate[J]. Chinese Journal of Synthetic Chemistry, 2003, 11(3): 230-232,236 |
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| Authors: | FAN Yu hua HAO Rui BI Cai feng MA Yu xiang |
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| Affiliation: | FAN Yu hua 1,2,HAO Rui 2,BI Cai feng 2,MA Yu xiang 2 |
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| Abstract: | Four new solid ternary complexes of lanthanide nitrates with potassium salt of Schiff base 2 hydroxy 1 naphthaldehyde methionine(KL) and phenanthroline(Phen) have been synthesized and characterized by elemental analysis, IR, UV, DTA TG and molar conductance. The compositions of the complexes were confirmed to be [Ln(L)(Phen)(NO 3)(H 2O)]NO 3(Ln=Gd,Dy,Er,Yb). Some properties of the complexes were studied. |
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| Keywords: | lanthanide nitrate Schiff base ternary complex |
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