Chlorination and oxidation of some sulfurcontaining tetrachloropyridine derivatives |
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Authors: | S. D. Moshchitskii G. A. Zalesskii Ya. N. Ivashchenko L. M. Yagupol'skii |
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Affiliation: | (1) Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev |
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Abstract: | In the chlorination of 4-methyl- and 4-chloroformylmethylenethiotetrachloropyridines, the chlorine atom enters the methyl or methylene group. In the case of the 4-(p-chlorobenzyl)-thio derivative, the molecule is cleaved to give tetrachloropyridine-4-sulfenyl chloride. Hydrogen peroxide oxidizes substituted benzyl- and ethoxycarbonylmethylenethiotetrachloropyridines to the corresponding sulfones, while nitric acid gives a mixture of tetrachloropyridinesulfonic acid and the corresponding benzole acid. quantitative yields (Table 2).Translated from Khimiya Geterotsiklicheskikh Soedinenii,No.8, pp. 1094–1098, August, 1972. |
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