Synthesis and structure of di(2-phenyl-8-quinolyl) diselenide and zinc bis[(2-phenyl-8-quinolyl)selenolate] |
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Authors: | E. Silina S. Belyakov J. Ashaks A. Tokmakov L. Pech D. Zaruma |
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Affiliation: | 1.Institute of Inorganic Chemistry,Riga Technological University,Salaspils,Latvia;2.Latvian Institute of Organic Synthesis,Riga,Latvia;3.Institute of Solid State Physics,Latvian University,Riga,Latvia |
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Abstract: | Di(2-phenyl-8-quinolyl) diselenide [2-(C6H5)C9H5NSe]2 and zinc bis[(2-phenyl-9-quinolyl)selenolate], Zn [2-(C6H5)C9H5NSe]2, have been synthesized. The molecular and crystal structure of the compounds were determined by X-ray structural analysis. The structures of the 2-phenyl-8-quinolylselenol ligand in the molecules of di(2-phenyl-8-quinolyl) diselenide and in the intracomplex compound of zinc are compared. The effect of the phenyl group in position 2 of the quinoline nucleus on the formation of the molecules and their packing in the crystal structure is discussed. |
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