Synthesis and structure of di(2-phenyl-8-quinolyl) diselenide and zinc bis[(2-phenyl-8-quinolyl)selenolate] |
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| Authors: | E Silina S Belyakov J Ashaks A Tokmakov L Pech D Zaruma |
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| Institution: | 1.Institute of Inorganic Chemistry,Riga Technological University,Salaspils,Latvia;2.Latvian Institute of Organic Synthesis,Riga,Latvia;3.Institute of Solid State Physics,Latvian University,Riga,Latvia |
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| Abstract: | Di(2-phenyl-8-quinolyl) diselenide 2-(C6H5)C9H5NSe]2 and zinc bis(2-phenyl-9-quinolyl)selenolate], Zn 2-(C6H5)C9H5NSe]2, have been synthesized. The molecular and crystal structure of the compounds were determined by X-ray structural analysis.
The structures of the 2-phenyl-8-quinolylselenol ligand in the molecules of di(2-phenyl-8-quinolyl) diselenide and in the
intracomplex compound of zinc are compared. The effect of the phenyl group in position 2 of the quinoline nucleus on the formation
of the molecules and their packing in the crystal structure is discussed. |
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