The addition of perfluoroalkanesulfinyl chlorides to alkoxyallenes |
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| Authors: | Ling-Jun Chen |
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| Institution: | Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China |
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| Abstract: | The addition reaction of perfluoroalkanesulfinyl chlorides to alkoxyallenes was achieved under mild conditions. Two kinds of perfluoroalkyl alkenyl sulfoxides, β-alkoxyvinyl perfluoroalkyl sulfoxides and α-perfluoroalkanesulfinyl enones or enals, were obtained selectively depending on the structure of alkoxyallenes. |
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| Keywords: | Perfluoroalkanesulfinyl chloride Alkoxyallene Alkenyl sulfoxide Addition reaction |
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