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2-Bromo-3,4,4-trichlorobut-3-enoates of certain natural alcohols, phenols, and oximes of carbonyl compounds
Authors:E. A. Dikusar  V. I. Potkin  N. G. Kozlov  S. K. Petkevich  N. V. Kovganko
Affiliation:(1) Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus’, Minsk, ul. Surganova, 13, Belarus;(2) Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus’, Minsk, ul. Akad. Kuprevicha, 5/2, Belarus
Abstract:Previously undescribed 2-bromo-3,4,4-trichlorobut-3-enoates 1b-23b were synthesized in 84–91% yield from natural alcohols including terpenes and steroids, plant phenols, and oximes of natural carbonyl compounds 1a-23a by reaction of 2-bromo-3,4,4-trichlorobut-3-enoyl chloride in the presence of pyridine. __________ Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 212–215, May–June, 2006.
Keywords:2-bromo-3,4,4-trichlorobut-3-enoyl chloride  2-bromo-3,4,4-trichlorobut-3-enoates  esters  terpene alcohols  steroidal alcohols  plant phenols  oximes  chemical modification
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